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La historia de la puzolana es un buen ejemplo de como la humanidad olvida y redescubre ciclicamente cosas que nunca debió olvidar.

Short History of Concrete
by Umberto Barbisan e Matteo Guardini

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The oldest known form of concrete is to be found in the Middle East and it dates back to 5600 BC; the Egyptians (XXVI Century BC) used mixed with straw to bind dried bricks, gypsum and lime mortars in stone masonry (in particular for the construction of pyramids).

The Greeks living in Crete and Cyprus used lime mortars as well (Eight Century BC), whereas Babylonians and Syrians used bitumen to construct stone and brick masonries.

The Ancient Greeks, similarly, used calcined limestone, while the Romans made the first concrete: mixed lime putty with brick dust or volcanic ash. They used it with stone to construct roadways, buildings and aqueducts.
The Romans used pozzolana, a particular type of sand from Pozzuoli, near the volcano Vesuvio (Southern Italy), to construct buildings of crucial importance, such as the Pantheon or the Colosseo.

- Pantheon J. Durm, Handbuch der Architektur, Stoccarda, 1905.

Pozzolana is an uncommon kind of sand which reacts chemically with lime and water, becoming a rocklike mass; furthermore, it is siliceous and aluminous and it reacts with calcium hydroxide to form compounds with cementation properties.
The domed Pantheon, constructed in the Second Century AD, is one of the structural masterpieces of Roman time: it has a sophisticated structure with a large number of voids, niches and small vaulted spaces aimed at reducing its weight; in particular the dome shows a thicker structure at its base, whereas its thickness tends to diminish gradually, according to the increased height of the dome (in other words, the dome thickness is inversely proportional to its height).
Pliny reported a mortar of lime and sand (one part of lime to four parts of sand), and Marco Vitruvio Pollione (First Century BC) reported a mixture of pozzolana and lime (two parts of pozzolana to one part of lime) and we have also an essay of him as regards the properties of concrete.
The name concrete comes from the Latin concretus, which means to grow together.

During the Middle Ages the quality of cementing materials deteriorated: lime and pozzolana were no longer used; they were reintroduced in the thirteen and fourteen centuries.
By the Fifteenth Century, Venetian constructors used the black lime of Abetone – an area near Vicenza (Northern Italy) - which is similar to pozzolana.
In 1499 Fra Giocondo used the pozzolana sand in the mortar of the pier of the Pont de Notre Dame in Paris.

In 1779 B. Higging was granted a patent for hydraulic cement used for exterior plastering.
In 1793 J. Smeaton found that the calcination of limestone containing clay produced a kind of lime that hardened under water; Smeaton used hydraulic lime to construct the Eddystone Lighthouse in Cornwall.

- The Eddystone Lighthouse in Cornwall by the interpretation of M. G. Sganzin, Nuovo corso completo di pubbliche costruzioni, Venezia, 1849.

In 1796 James Parker patented a special type of natural hydraulic cement – called Roman Cement – obtained through the calcination of nodules of impure limestone containing clay. A similar process was used in France in 1802.
In 1812 L. Vicat prepared an artificial hydraulic lime by calcining artificial mixtures of limestone and clay.
In 1818 natural cement was produced in the United States and M. de Saint Leger was granted patents for hydraulic cement. In 1822 J. Frost launched an artificial hydraulic lime called British Cement.
The year 1824 is of paramount importance in the history of concrete: in 1824 J. Aspdin improved the so called Portland Cement – named after the high quality stones quarried at Portland, in England - by burning together a mixture of chalk and clay until carbon dioxide was driven off; Aspdin’s cement was an immediate success.
In 1828 I. K. Brunel was the first architect who used Portland Cement for the constriction of the Thames Tunnel, whereas in Germany systematic tests of the compressive and tensile strength of cement began in 1836.
J. L. Lambot built in Southern France, in 1848, a small concrete boat (later he reinforced his boats with iron bars and wire mesh) and in the 1890s the Italian C. Gabellini began to build concrete ships as well.


Notas :

1) El cemento puzolánico CP-40 debe contener un promedio de 70% puzolana y 30% cal, siendo su finura similar a la del cemento portland.

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Ver fichero PFD de la investigación de Murat.
(en francés)
Mortero de Cal
Horno de Cal
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